Effect of Cl, Br, 14N, 31P, 19F etc to NMR spectra

Cl and Br have huge quadrupolar moments and their effect to other nuclei in the neighborhood can be considered non-existent.

The effect of 14N is dependent on its electron environment.  3-coordinated 14N has a large asymmetry in electron structure and thus the quadrupolar coupling is large, thus usually has negligible effect to neighboring nuclei.  4-coordinated 14N is more electronically symmetric and has a smaller quadrupolar coupling, therefore can split neighboring nuclei.  In this case, the neighboring 13C will be split into a triplet with intensity ratio of 1:1:1.  The splitting distance gives you the J-coupling constant between the nucleus of interest and the 14N.

2H has a fairly small quadrupolar coupling so it almost always split neighboring 13C to a 1:1:1 triplet.  Those who have run 13C spectra of samples with CDCl3 must be quite familiar with those triplets!

If you use acetone-d6 or dmso-d6 as solvent, the solvent peak on 13C spectra is not triplet but a septulet.  Do you know why and can you predict the intensity ratio of the 7 peaks?

31P and 19F have a spin of 1/2 and will always split neighboring nuclei to a 1:1 doublet.  If multiple 19F are present in the neighborhood, your 13C peaks will have a more complex splitting.